Product ID:PLEXIGLAS V GRADE ACRYLIC RESIN
MSDS Date:07/28/1994
FSC:9330
NIIN:00N066918
MSDS Number: CBDZQ

ROHM & HAAS CO

100 INDEPENDENCE MALL WEST
PHILADELPHIA, PA 19105-2399
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 215-592-3000

Cage: GO264

ROHM AND HAAS CO

PHILADELPHIA, PA 19106-2399 US

Telephone: 215-592-2521/215-592-3000

Cage: 77902

2-PROPANOIC ACID,2-METHYL-METHYL ESTER POLYMER W/ (LUCITE

CAS: 9010-88-2

Fraction By Weight: 99.3%

OSHA PEL N/K

ACGIH TLV: N/K

METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE) (SARA

CAS: 80-62-6

RTECS: OZ5075000

Fraction By Weight: <0.7%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACRYLIC ACID, ETHYL ESTER; (ETHYL ACRYLATE) (SARA 313)

CAS: 140-88-5

RTECS: AT0700000

Fraction By Weight: TRACE

OSHA PEL 25 PPM

ACGIH TLV: 5 PPM; 15 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WEAR NIOSH/MSHA

RTECS: 9999999ZZ

NIOSH/MSHA APPRVD (OR EQUIV) FULL-FACEPIECE AIRLINE

RTECS: 9999999ZZ

AIR-PURIFYING RESPS SHOULD BE EQUIPPED W/NIOSH/MSHA

RTECS: 9999999ZZ

A MANUAL OF RECOM PRACTICE

RTECS: 9999999ZZ

& MAINTENANCE OF EXHAUST SYSTEMS.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF MONOMER VAPOR FROM
HEATED PRODUCT CAN CAUSE IRRITATION OF NOSE, THROAT AND LUNGS,
DIZZINESS, HEADACHE, NAUSEA. MONOMER VAPORS FROM HEATED PRODUCT CAN
CAUSE EYE AND SKIN IRRITATION. THIS INFORMATION IS BASED ON
TOXICITY PROFILES OF SIMILAR MATERIALS OR ON COMPONENTS PRESENT IN
THIS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MATERIAL. THIS PRODUCT CONTAINS TRACE
LEVELS OF ETHYL ACRYLATE WHICH IS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: MOVE TO FRESH AIR. EYES:
FLUSH EYES WITH A LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES.
CONSULT MD IF IRRITATION PERSISTS. SKIN: CONSULT MD IF IRRITATION P
ERSISTS.

Extinguishing Media:USE THE FOLLOWING EXTINGUISHING MEDIA WHEN FIGHTING
FIRES INVOLVING THIS MATL:CARBON DIOXIDE, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL AS SOLD IS COMBUSTIBLE; BURNS
VIGOROUSLY WITH INTENSE HEAT.

Spill Release Procedures:WEAR GLOVES MADE OF COTTON, CANVAS OR LEATHER.
ADDNL PERSONAL PROT EQUIP SHOULD INCLUDE SFTY GLASSES (ANSI
Z87.1/APPRVD EQUIV). FLOOR MAY BE SLIPPERY; USE CARE TO AVOID
FALLING. TRANSFER SPILLED MATL TO SUITABLE CNTNRS FOR RECOVERY OR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MATL IS NOT HAZ UNDER NORM STOR
CNDTNS. HOWEVER, ALL MATLS OF THIS TYPE RELS SOME MONOMER
VAPS/GASES WHEN STORED FOR PRLNGD PERIODS AT (SUPDAT)
Other Precautions:THIS MATERIAL CAN RELEASE MONOMER VAPORS OR GASES
WHEN HEATED TO HIGH TEMPERATURES DURING PROCESSING, CUTTING OR
MACHINING. SEE VENTILATION SECTION FOR TYPES OF VENTILATION
REQUIRED.

Respiratory Protection:RESP PROT PROGRAM MEETING OSHA 1910.134 & ANSI
Z88.2 REQS MUST BE FOLLOWED WHENEVER WORKPLACE CNDTNS WARRANT RESP
USE. NONE REQD IF AIRBORNE CONCS ARE MAINTAINED BELOW EXPOS LIM
LISTED. UP TO 10 TIMES TWA/TLV:WEAR NIOSH/MSHA APPRVD (SUPDAT)
Ventilation:USE LOC EXHST VENT W/MIN CAPTURE VELOCITY OF 100 FT/MIN
(0.5 M/SEC) AT POINT OF VAP EVOLUTION. REFER TO CURRENT (ING 7)
Protective Gloves:COTTON, CANVAS OR LEATHER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV: 1.15-1.19 (H*2O=1). HNDLG/STOR PRECS: ELEVATED TEMPS. AVOID
TEMP EXTREMES DURING STORAGE; AMBIENT TEMP PREF. RESP PROT: (OR
EQUIV) HALF-MASK, AIR-PURIFYING RESP. UP TO 1000 PPM ORG VAP: WEA R
NIOSH/MSHA APPRVD (OR EQUIV) FULL-FACEPIECE, AIR PURIFYING RESP.
(ING 4)

Melt/Freeze Pt:M.P/F.P Text:270F,132C
Spec Gravity:SUPDAT
Appearance and Odor:CLEAR TO OPAQUE PELLETS, VARIOUS COLORS; MILD ODOR.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ACIDS, ALKALIES AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 260C/500F FOR
PROLONGED PERIODS TO PREVENT SLOW DECOMPOSITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD
ACRYLIC MONOMERS.

Waste Disposal Methods:FOR DISPOSAL, INCINERATE THIS MATERIAL AT A
FACILITY THAT COMPLIES WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.